Intramolecular noncovalent trans ring restricting free rotation of σ single bond enhances photosynthesis of hydrogen peroxide

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Proceedings of the National Academy of Sciences, Volume 123, Number 6, February 2026.
SignificanceCovalent organic frameworks (COFs) offer a promising molecular platform for the direct solar-to-chemical conversion of atmospheric oxygen and water to hydrogen peroxide (H2O2). However, photogenerated charge carrier recombination…

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